Exhibit 4.2

Execution Copy

HUNTSMAN INTERNATIONAL LLC

AND

THE GUARANTORS NAMED HEREIN,

AND

THE BANK OF NEW YORK

as Trustee

SUPPLEMENTAL INDENTURE

Dated as of December 20, 2005

Indenture

Dated as of March 13, 2001

10¹/₈% Senior Subordinated Notes due 2009

SUPPLEMENTAL INDENTURE, dated as of December 20, 2005 (this “Supplemental Indenture”), between HUNTSMAN INTERNATIONAL LLC, a Delaware limited liability company (the “Company”), the Guarantors named herein and THE BANK OF NEW YORK, a New York banking corporation duly organized under the laws of the State of New York, as trustee (the “Trustee”). All capitalized terms used and not defined herein shall have the respective meanings assigned to them in the Indenture.

WHEREAS, the Company, the Guarantors and the Trustee are parties to an Indenture, dated as of March 13, 2001, as supplemented by the First Supplemental Indenture thereto dated January 11, 2002 and the Supplemental Indenture thereto dated August 16, 2005 (the “Indenture”), pursuant to which the Company issued its 10¹/₈% Senior Subordinated Notes due 2009 (the “Notes”);

WHEREAS, on the date hereof, all of the membership interests of Huntsman Advanced Materials Holdings LLC, a Delaware limited liability company (“HAMH”), have been contributed to the Company (the “Contribution”);

WHEREAS, in connection with the Contribution, HAMH and the Subsidiaries of HAMH who are listed on the signature page hereto under the heading “New Guarantors” (the “New Guarantors”) wish to become Guarantors under the Indenture in accordance with Section 4.19 and Article XI thereof;

WHEREAS, Section 9.01 of the Indenture provides that the Company, the Guarantors and the Trustee may amend the Indenture by means of this Supplemental Indenture without the consent of the holders of Notes for the foregoing purposes;

WHEREAS, the Company has delivered to the Trustee the required Officers’ Certificate and Opinion of Counsel in connection with the execution and delivery of this Supplemental Indenture; and

WHEREAS, the execution and delivery of this Supplemental Indenture have been duly authorized and all conditions and requirements necessary to make this Supplemental Indenture a valid and binding agreement have been duly performed and complied with;

NOW, THEREFORE, for and in consideration of the premises and other good and valuable consideration, the receipt and sufficiency of which are hereby acknowledged, it is mutually covenanted and agreed, for the equal proportionate benefit of all Holders of the Notes, as follows:

ARTICLE I
GUARANTEES

Section 1.1 Guarantees. Each New Guarantor hereby, in compliance with Section 4.19 of the Indenture, Guarantees the obligations of the Company under the Indenture and the Notes in the manner specified in Section 11.01 of the Indenture on a subordinated basis as provided in Article XII of the Indenture, and becomes a party to the Indenture as a Guarantor, in each case subject to all of the rights, obligations and other provisions and limitations (including release provisions) of the Indenture relating to Guarantors.

ARTICLE II
MISCELLANEOUS PROVISIONS

Section 2.1 Upon execution and delivery of this Supplemental Indenture, the terms and conditions of this Supplemental Indenture shall be part of the terms and conditions of the Indenture for any and all purposes, and all the terms and conditions of both shall be read together as though they

constitute one and the same instrument, except that in case of conflict, the provisions of this Supplemental Indenture will control.

Section 2.2 Each of the Company, the Guarantors and the Trustee hereby confirms and reaffirms the Indenture, as amended and supplemented by this Supplemental Indenture.

Section 2.3 The parties may sign any number of copies of this Supplemental Indenture. Each signed copy shall be an original, but all of them together shall represent the same agreement. One signed copy is enough to prove this Supplemental Indenture.

Section 2.4 This Supplemental Indenture shall be governed by, and construed in accordance with, the laws of the State of New York.

Section 2.5 The recitals contained herein shall be taken as the statements of the Company or the Guarantors, as applicable, and the Trustee assumes no responsibility for their correctness. The Trustee shall not be liable or responsible for the validity or sufficiency of this Supplemental Indenture or the due authorization of this Supplemental Indenture by the Company or the Guarantors. In entering into this Supplemental Indenture, the Trustee shall be entitled to the benefit of every provision of the Indenture relating to the conduct of, affecting the liability of or affording protection to the Trustee, whether or not elsewhere herein so provided.

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EXISTING GUARANTORS:

	Airstar Corporation
	Eurofuels LLC
	Eurostar Industries LLC
	Huntsman Australia Inc.
	Huntsman Chemical Company LLC
	Huntsman Chemical Finance Corporation
	Huntsman Chemical Purchasing Corporation
	Huntsman EA Holdings LLC
	Huntsman Enterprises, Inc.
	Huntsman Ethyleneamines Ltd.
			By:	Huntsman EA Holdings LLC,
				its General Partner
	Huntsman Expandable Polymers Company, LC
			By:	Huntsman International Chemicals Corporation,
				its Sole Member and Manager
	Huntsman Family Corporation
	Huntsman Group Holdings Finance Corporation
	Huntsman Group Intellectual Property Holdings Corporation
	Huntsman Headquarters Corporation
	Huntsman International Chemicals Corporation
	Huntsman International Financial LLC
	Huntsman International Fuels, L.P.
			By:	Eurofuels LLC,
				its General Partner
	Huntsman International Services Corporation
	Huntsman International Trading Corporation
	Huntsman MA Investment Corporation
	Huntsman MA Services Corporation
	Huntsman Petrochemical Canada Holdings Corporation
	Huntsman Petrochemical Corporation
	Huntsman Petrochemical Finance Corporation
	Huntsman Petrochemical Purchasing Corporation
	Huntsman Polymers Corporation
	Huntsman Polymers Holdings Corporation
	Huntsman Procurement Corporation
	Huntsman Propylene Oxide Holdings LLC
	Huntsman Propylene Oxide Ltd.
			By:	Huntsman Propylene Oxide Holdings LLC,
				its General Partner
	Huntsman Purchasing, Ltd.
		By:		Huntsman Procurement Corporation,
				its General Partner
	Huntsman Texas Holdings LLC
	JK Holdings Corporation
	Petrostar Industries LLC
	Polymer Materials Inc.


				By:	/s/ Sean Douglas
				Name:		Sean Douglas
				Title:		Vice President

Huntsman Fuels, L.P.

By:

Petrostar Fuels LLC,

its General Partner

Petrostar Fuels LLC

Executed as a deed by

Tioxide Americas Inc.

Troy M. Keller

for and on behalf of

Tioxide Americas Inc.

By:

/s/ Troy M. Keller

in the presence of

Name:

Troy M. Keller

Title:

Assistant Secretary

/s/ Mary K. Klinefelter

Witness

Tioxide Group

By:

/s/ Peter R. Huntsman

Name:

Peter R. Huntsman

Title:

Director

By:

/s/ J. Kimo Esplin

Name:

J. Kimo Esplin

Title:

Director

NEW GUARANTORS:

Huntsman Advanced Materials Americas Inc.

Huntsman Advanced Materials Holdings LLC

Huntsman Advanced Materials LLC

By:

Name:

Sean Douglas

Title:

Vice President

HUNTSMAN INTERNATIONAL LLC


By:		/s/ Sean Douglas
	Name: Sean Douglas
	Title: Vice President and Treasurer

	THE BANK OF NEW YORK
	as Trustee


	By:	/s/ Luis Perez
	Name: Luis Perez
	Title: Assistant Vice President