Exhibit 4.20

EXECUTION VERSION

HUNTSMAN INTERNATIONAL LLC

AND

THE GUARANTORS NAMED HEREIN,

AND

WELLS FARGO BANK, NATIONAL ASSOCIATION

as Trustee

SUPPLEMENTAL INDENTURE

Dated as of February 13, 2013

Indenture

Dated as of November 19, 2012

4.875% Senior Notes due 2020

SUPPLEMENTAL INDENTURE (this “Supplemental Indenture”), dated as of February 13, 2013, among Huntsman Australia Holdings LLC and Huntsman Surfactants Technology Corporation (the “Guaranteeing Subsidiaries”), subsidiaries of Huntsman International LLC (or its permitted successor), a Delaware limited liability company (the “Company”), the Company, the other Guarantors (as defined in the Indenture referred to herein) and Wells Fargo Bank, National Association, a national banking association, as trustee under the Indenture referred to below (the “Trustee”).

W I T N E S S E T H

WHEREAS, the Company has heretofore executed and delivered to the Trustee an indenture (the “Indenture”), dated as of November 19, 2012 providing for the issuance of 4.875% Senior Notes due 2020 (the “Notes”);

WHEREAS, the Indenture provides that under certain circumstances the Guaranteeing Subsidiaries shall execute and deliver to the Trustee a supplemental indenture pursuant to which the Guaranteeing Subsidiaries shall unconditionally guarantee all of the Company’s obligations under the Notes and the Indenture on the terms and conditions set forth herein (the “Note Guarantees”); and

WHEREAS, pursuant to Section 9.01 of the Indenture, the Trustee is authorized to execute and deliver this Supplemental Indenture.

NOW, THEREFORE, in consideration of the foregoing and for other good and valuable consideration, the receipt of which is hereby acknowledged, the Guaranteeing Subsidiaries and the Trustee mutually covenant and agree for the equal and ratable benefit of the Holders of the Notes as follows:

1. CAPITALIZED TERMS. Capitalized terms used herein without definition shall have the meanings assigned to them in the Indenture.

2. AGREEMENT TO GUARANTEE. The Guaranteeing Subsidiaries hereby agree to provide unconditional Guarantees on the terms and subject to the conditions set forth in the Note Guarantees and in the Indenture including but not limited to Article 10 thereof.

4. NO RECOURSE AGAINST OTHERS. No director, officer, employee, incorporator or stockholder of the Company or any Guarantor, as such, will have any liability for any obligations of the Company or the Guarantors under the Notes, this Indenture, the Note Guarantees or for any claim based on, in respect of, or by reason of, such obligations or their creation. Each Holder of Notes by accepting a Note waives and releases all such liability. The waiver and release are part of the consideration for issuance of the Notes. The waiver may not be effective to waive liabilities under the federal securities laws.

5. GOVERNING LAW. THE INTERNAL LAW OF THE STATE OF NEW YORK WILL GOVERN AND BE USED TO CONSTRUE THIS SUPPLEMENTAL INDENTURE WITHOUT GIVING EFFECT TO APPLICABLE PRINCIPLES OF CONFLICTS OF LAW TO THE EXTENT THAT THE APPLICATION OF THE LAWS OF ANOTHER JURISDICTION WOULD BE REQUIRED THEREBY.

6. COUNTERPARTS. The parties may sign any number of copies of this Supplemental Indenture. Each signed copy will be an original, but all of them together represent the same agreement. The exchange of copies of this Supplemental Indenture and of signature pages by facsimile or PDF transmission shall constitute effective execution and delivery of this Supplemental Indenture as to the parties hereto and may be used in lieu of the original Indenture for all purposes. Signatures of the parties hereto transmitted by facsimile or PDF shall be deemed to be their original signatures for all purposes.

7. EFFECT OF HEADINGS. The Section headings herein are for convenience of reference only, are not to be considered a part of this Supplemental Indenture and will in no way modify or restrict any of the terms or provisions hereof.

8. THE TRUSTEE. The Trustee shall not be responsible in any manner whatsoever for or in respect of the validity or sufficiency of this Supplemental Indenture or for or in respect of the recitals contained herein, all of which recitals are made solely by the Guaranteeing Subsidiaries and the Company.

GUARANTEEING SUBSIDIARIES:

	HUNTSMAN AUSTRALIA HOLDINGS LLC

	By:	/s/ John R. Heskett
	Name:	John R. Heskett
	Title:	Vice President, Planning and Treasurer


	HUNTSMAN SURFACTANTS TECHNOLOGY CORPORATION

	By:	/s/ John R. Heskett
	Name:	John R. Heskett
	Title:	Vice President, Planning and Treasurer

Supplemental Indenture — 2020 Senior Notes

EXISTING GUARANTORS:

	AIRSTAR CORPORATION
	HUNTSMAN ADVANCED MATERIALS AMERICAS LLC
	HUNTSMAN ADVANCED MATERIALS LLC
	HUNTSMAN AUSTRALIA LLC
	HUNTSMAN CHEMICAL PURCHASING LLC
	HUNTSMAN ENTERPRISES LLC
	HUNTSMAN ETHYLENEAMINES LLC
	HUNTSMAN FUELS LLC
	HUNTSMAN INTERNATIONAL FINANCIAL LLC
	HUNTSMAN INTERNATIONAL FUELS LLC
	HUNTSMAN INTERNATIONAL TRADING CORPORATION
	HUNTSMAN MA INVESTMENT CORPORATION
	HUNTSMAN MA SERVICES CORPORATION
	HUNTSMAN PETROCHEMICAL LLC
	HUNTSMAN PETROCHEMICAL PURCHASING LLC
	HUNTSMAN PROCUREMENT LLC
	HUNTSMAN PROPYLENE OXIDE LLC
	HUNTSMAN PURCHASING, LTD.
	By:	Huntsman Procurement LLC, its General Partner
	POLYMER MATERIALS INC.
	TIOXIDE AMERICAS (HOLDINGS) LLC


	By:	/s/ John R. Heskett
	Name:	John R. Heskett
	Title:	Vice President, Planning and Treasurer

	TIOXIDE AMERICAS LLC
Executed as a Deed by

for and on behalf of John R. Heskett	By:	/s/ John R. Heskett
Tioxide Americas LLC		Name:	John R. Heskett
in the presence of		Title:	Vice President, Planning and Treasurer

/s/ Josh Erekson
Witness

Supplemental Indenture — 2020 Senior Notes

Signed as a Deed by		TIOXIDE GROUP

as attorney for TIOXIDE GROUP		By:	/s/ John R. Heskett
under a power of attorney dated			John R. Heskett, as attorney for
February 8, 2013			TIOXIDE GROUP
in the presence of:

/s/ Josh Erekson
Witness
Name: Josh Erekson
Address:	500 Huntsman Way
	Salt Lake City, UT 84108
Occupation: Attorney

Supplemental Indenture — 2020 Senior Notes

	HUNTSMAN INTERNATIONAL LLC


	By:	/s/ John R. Heskett
	Name:	John R. Heskett
	Title:	Vice President, Planning and Treasurer

	WELLS FARGO BANK, NATIONAL ASSOCIATION, as Trustee,


	By:	/s/ Lynn M . Steiner
	Name:	Lynn M. Steiner
	Title:	Vice President